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β-Nickel hydroxide cathode material for nano-suspension redox flow batteries

Yue LI, Cheng HE, Elena V. TIMOFEEVA, Yujia DING, Javier PARRONDO, Carlo SEGRE, Vijay RAMANI

《能源前沿（英文）》 2017年 第11卷 第3期   页码 401-409 doi: 10.1007/s11708-017-0496-0

摘要： As part of an effort to build a prototype flow battery system using a nano-suspension containing β-Ni(OH) nanoparticles as the cathode material, nano-sized β-Ni(OH) particles with well-controlled particle size and morphology were synthesized via the one-step precipitation of a NiCl precursor. The composition and morphology of the nanoparticles were characterized by scanning electronic microscopy (SEM) and X-ray diffraction (XRD). The XRD patterns confirmed that β-Ni(OH) was successfully synthesized, while SEM results showed that the particle sizes range from 70 to 150 nm. To ensure that Ni(OH) could be employed in the nano-suspension flow battery, the electrochemical performance of the synthesized β-Ni(OH) was initially tested in pouch cells through charge/discharge cycling. The phase transformations occurring during charge/discharge were investigated using X-ray absorption spectroscopy to obtain the shift in the oxidation state of Ni (X-ray adsorption near edge structure, XANES) and the distances between Ni and surrounding atoms in charged and discharged states (extended X-ray absorption fine structure, EXAFS). XANES results indicated that the electrode in the discharged state was a mixture of phases because the edge position did not shift back completely. XAFS results further proved that the discharge capacity was provided by β-NiOOH and the ratio between β-Ni(OH) and g-NiOOH in the electrode in the discharged state was 71:29. Preliminary nano-suspension tests in a lab-scale cell were conducted to understand the behavior of the nano-suspension during charge/discharge cycling and to optimize the operating conditions.

关键词： nano-suspension flow battery     β-Ni(OH)2     scanning electronic microscopy (SEM)     X-ray diffraction (XRD)     X-ray adsorption near edge structure (XANES)     extended X-ray absorption fine structure (EXAFS)    

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Optimal design and development of PV-wind-battery based nano-grid system: A field-on-laboratory demonstration

B. TUDU, K. K. MANDAL, N. CHAKRABORTY

《能源前沿（英文）》 2019年 第13卷 第2期   页码 269-283 doi: 10.1007/s11708-018-0573-z

摘要： The present paper has disseminated the design approach, project implementation, and economics of a nano-grid system. The deployment of the system is envisioned to acculturate the renewable technology into Indian society by field-on-laboratory demonstration (FOLD) and “bridge the gaps between research, development, and implementation.” The system consists of a solar photovoltaic (PV) (2.4 kWp), a wind turbine (3.2 kWp), and a battery bank (400 Ah). Initially, a prefeasibility study is conducted using the well-established HOMER (hybrid optimization model for electric renewable) software developed by the National Renewable Energy Laboratory (NREL), USA. The feasibility study indicates that the optimal capacity for the nano-grid system consists of a 2.16 kWp solar PV, a 3 kWp wind turbine, a 1.44 kW inverter, and a 24 kWh battery bank. The total net present cost (TNPC) and cost of energy (COE) of the system are US$20789.85 and US$0.673/kWh, respectively. However, the hybrid system consisting of a 2.4 kWp of solar PV, a 3.2 kWp of wind turbine, a 3 kVA of inverter, and a 400 Ah of battery bank has been installed due to unavailability of system components of desired values and to enhance the reliability of the system. The TNPC and COE of the system installed are found to be US$20073.63 and US$0.635/kWh, respectively and both costs are largely influenced by battery cost. Besides, this paper has illustrated the installation details of each component as well as of the system. Moreover, it has discussed the detailed cost breakup of the system. Furthermore, the performance of the system has been investigated and validated with the simulation results. It is observed that the power generated from the PV system is quite significant and is almost uniform over the year. Contrary to this, a trivial wind velocity prevails over the year apart from the month of April, May, and June, so does the power yield. This research demonstration provides a pathway for future planning of scaled-up hybrid energy systems or microgrid in this region of India or regions of similar topography.

关键词： photovoltaic (PV)     wind     battery     nano-grid     hybrid optimization model for electric renewable (HOMER)     field-on-lab demonstration (FOLD)    

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Characterization and comparison of organic functional groups effects on electrolyte performance for vanadium redox flowbattery

《化学科学与工程前沿（英文）》 2023年 第17卷 第9期   页码 1221-1230 doi: 10.1007/s11705-023-2298-8

摘要： The vanadium redox flow battery with a safe and capacity-controllable large-scale energy storage system offers a new method for the sustainability. In this case, acetic acid, methane sulfonic acid, sulfonic acid, amino methane sulfonic acid, and taurine are used to overcome the low electrolyte energy density and stability limitations, as well as to investigate the effects of various organic functional groups on the vanadium redox flow battery. When compared to the pristine electrolyte (0.22 Ah, 5.0 Wh·L–1, 85.0%), the results show that taurine has the advantage of maintaining vanadium ion concentrations, discharge capacity (1.43 Ah), energy density (33.9 Wh·L–1), and energy efficiency (90.5%) even after several cycles. The acetic acid electrolyte is more conducive to the low-temperature stability of the V(II) electrolyte (177 h at −25 °C) than pristine (82 h at −2 °C). The –SO3H group, specifically the coaction of the –NH2 and –SO3H groups, improves electrolyte stability. The –NH2 and –COOH additive groups improved conductivity and electrochemical activity.

关键词： vanadium redox flow battery     functional groups     organic additives     energy density     stability    

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Pressure drop analysis on the positive half-cell of a cerium redox flow battery using computational fluid

Fernando F. Rivera, Berenice Miranda-Alcántara, Germán Orozco, Carlos Ponce de León, Luis F. Arenas

《化学科学与工程前沿（英文）》 2021年 第15卷 第2期   页码 399-409 doi: 10.1007/s11705-020-1934-9

摘要： Description of electrolyte fluid dynamics in the electrode compartments by mathematical models can be a powerful tool in the development of redox flow batteries (RFBs) and other electrochemical reactors. In order to determine their predictive capability, turbulent Reynolds-averaged Navier-Stokes (RANS) and free flow plus porous media (Brinkman) models were applied to compute local fluid velocities taking place in a rectangular channel electrochemical flow cell used as the positive half-cell of a cerium-based RFB for laboratory studies. Two different platinized titanium electrodes were considered, a plate plus a turbulence promoter and an expanded metal mesh. Calculated pressure drop was validated against experimental data obtained with typical cerium electrolytes. It was found that the pressure drop values were better described by the RANS approach, whereas the validity of Brinkman equations was strongly dependent on porosity and permeability values of the porous media.

关键词： CFD simulation     porous media     porous electrode     pressure drop     redox flow battery    

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Redox flow batteries—Concepts and chemistries for cost-effective energy storage

Matthäa Verena HOLLAND-CUNZ, Faye CORDING, Jochen FRIEDL, Ulrich STIMMING

《能源前沿（英文）》 2018年 第12卷 第2期   页码 198-224 doi: 10.1007/s11708-018-0552-4

摘要： Electrochemical energy storage is one of the few options to store the energy from intermittent renewable energy sources like wind and solar. Redox flow batteries (RFBs) are such an energy storage system, which has favorable features over other battery technologies, e.g. solid state batteries, due to their inherent safety and the independent scaling of energy and power content. However, because of their low energy-density, low power-density, and the cost of components such as redox species and membranes, commercialised RFB systems like the all-vanadium chemistry cannot make full use of the inherent advantages over other systems. In principle, there are three pathways to improve RFBs and to make them viable for large scale application: First, to employ electrolytes with higher energy density. This goal can be achieved by increasing the concentration of redox species, employing redox species that store more than one electron or by increasing the cell voltage. Second, to enhance the power output of the battery cells by using high kinetic redox species, increasing the cell voltage, implementing novel cell designs or membranes with lower resistance. The first two means reduce the electrode surface area needed to supply a certain power output, thereby bringing down costs for expensive components such as membranes. Third, to reduce the costs of single or multiple components such as redox species or membranes. To achieve these objectives it is necessary to develop new battery chemistries and cell configurations. In this review, a comparison of promising cell chemistries is focused on, be they all-liquid, slurries or hybrids combining liquid, gas and solid phases. The aim is to elucidate which redox-system is most favorable in terms of energy-density, power-density and capital cost. Besides, the choice of solvent and the selection of an inorganic or organic redox couples with the entailing consequences are discussed.

关键词： electrochemical energy storage     redox flow battery     vanadium    

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End-of-life batteries management and material flow analysis in South Korea

Hyunhee Kim, Yong-Chul Jang, Yeonjung Hwang, Youngjae Ko, Hyunmyeong Yun

《环境科学与工程前沿（英文）》 2018年 第12卷 第3期 doi: 10.1007/s11783-018-1019-x

摘要： Consumers increasingly have worn-out batteries as electrical and electronic equipment with new technical developments are introduced into the market and quickly replace older models. As a result, large amounts of end-of-life (EOL) or waste batteries are generated. Such batteries may contain a variety of materials that includes valuable resources as well as toxic elements. Thus, the proper recycling and management of batteries is very important from the perspective of resource conservation and environmental effect. The collection and recycling of EOL batteries is relatively low in South Korea compared to other countries, although an extended producer responsibility (EPR) policy was adopted for battery recycling in 2003. In this study, the management and material flow of EOL batteries is presented to determine potential problems and quantitative flow, based on literature review, site visits to battery recycling facilities, and interviews with experts in the Korea Battery Recycling Association (KBRA), manufacturers, and regulators in government. The results show that approximately 558 tons of manganese-alkaline batteries, the largest fraction among recycling target items, was disposed in landfills or incinerators in 2015, while approximately 2,000 tons of batteries were recovered at a recycling facility by simple sorting and crushing processes. By raising environmental awareness, more diverse and effective collection systems could be established for consumers to easily dispose of EOL batteries in many places. Producers, retailers and distributors in South Korea should also play an important role in the collection of EOL batteries from consumers. Lithium-ion batteries from many electronic devices must be included in the EPR system for resource recovery.

关键词： End-of-life battery     Recycling     Material flow analysis (MFA)     Extended producer responsibility (EPR)     Resource recovery    

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用于固定式大规模储能的液流电池

尹彦斌, 李先锋

《工程（英文）》 2023年 第21卷 第2期   页码 42-44 doi: 10.1016/j.eng.2022.10.007

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Cumulant-based correlated probabilistic load flow considering photovoltaic generation and electric vehicle

Nitesh Ganesh BHAT, B. Rajanarayan PRUSTY, Debashisha JENA

《能源前沿（英文）》 2017年 第11卷 第2期   页码 184-196 doi: 10.1007/s11708-017-0465-7

摘要： This paper applies a cumulant-based analytical method for probabilistic load flow (PLF) assessment in transmission and distribution systems. The uncertainties pertaining to photovoltaic generations and aggregate bus load powers are probabilistically modeled in the case of transmission systems. In the case of distribution systems, the uncertainties pertaining to plug-in hybrid electric vehicle and battery electric vehicle charging demands in residential community as well as charging stations are probabilistically modeled. The probability distributions of the result variables (bus voltages and branch power flows) pertaining to these inputs are accurately established. The multiple input correlation cases are incorporated. Simultaneously, the performance of the proposed method is demonstrated on a modified Ward-Hale 6-bus system and an IEEE 14-bus transmission system as well as on a modified IEEE 69-bus radial and an IEEE 33-bus mesh distribution system. The results of the proposed method are compared with that of Monte-Carlo simulation.

关键词： battery electric vehicle     extended cumulant method     photovoltaic generation     plug-in hybrid electric vehicle     probabilistic load flow    

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A brief review on key technologies in the battery management system of electric vehicles

Kailong LIU, Kang LI, Qiao PENG, Cheng ZHANG

《机械工程前沿（英文）》 2019年 第14卷 第1期   页码 47-64 doi: 10.1007/s11465-018-0516-8

摘要： Batteries have been widely applied in many high-power applications, such as electric vehicles (EVs) and hybrid electric vehicles, where a suitable battery management system (BMS) is vital in ensuring safe and reliable operation of batteries. This paper aims to give a brief review on several key technologies of BMS, including battery modelling, state estimation and battery charging. First, popular battery types used in EVs are surveyed, followed by the introduction of key technologies used in BMS. Various battery models, including the electric model, thermal model and coupled electro-thermal model are reviewed. Then, battery state estimations for the state of charge, state of health and internal temperature are comprehensively surveyed. Finally, several key and traditional battery charging approaches with associated optimization methods are discussed.

关键词： battery management system     battery modelling     battery state estimation     battery charging    

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Investigations concerning seismic response control of self-anchored suspension bridge with MR dampers

YANG Menggang, HU Jianhua

《结构与土木工程前沿（英文）》 2008年 第2卷 第1期   页码 43-48 doi: 10.1007/s11709-008-0011-0

摘要： To mitigate the seismic response of self-anchored suspension bridges, equations of motion governing the coupled system of bridge- magneto-rheological (MR) dampers subject to seismic excitation are formulated by employing the phenomenological model of MR dampers. A corresponding computer program is developed and employed for studying the seismic response control of a self-anchored suspension bridge with a main span of 350 m. The effect of variable current and number of dampers on seismic response control is investigated. The numerical results indicate the longitudinal displacement of the tower top and bridge girder decrease with the increase in input current and number of MR dampers attached longitudinally at the tower-girder connections, and the internal forces of the tower are effectively attenuated as well. It appears that small electronic current (0.5 A in this study) may sufficiently attenuate the seismic responses for practical engineering applications.

关键词： longitudinal displacement     corresponding computer     excitation     phenomenological     self-anchored suspension    

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Mechanical performance analysis and stiffness test of a new type of suspension bridge

《结构与土木工程前沿（英文）》 2021年 第15卷 第5期   页码 1160-1180 doi: 10.1007/s11709-021-0760-6

摘要： A new type of suspension bridge is proposed based on the gravity stiffness principle. Compared with a conventional suspension bridge, the proposed bridge adds rigid webs and cross braces. The rigid webs connect the main cable and main girder to form a truss that can improve the bending stiffness of the bridge. The cross braces connect the main cables to form a closed space truss structure that can improve the torsional stiffness of the bridge. The rigid webs and cross braces are installed after the construction of a conventional suspension bridge is completed to resist different loads with different structural forms. A new type of railway suspension bridge with a span of 340 m and a highway suspension bridge with a span of 1020 m were designed and analysed using the finite element method. The stress, deflection of the girders, unbalanced forces of the main towers, and natural frequencies were compared with those of conventional suspension bridges. A stiffness test was carried out on the new type of suspension bridge with a small span, and the results were compared with those for a conventional bridge. The results showed that the new suspension bridge had a better performance than the conventional suspension bridge.

关键词： new type of suspension bridge     stiffness test     mechanical performance     railway bridge     space truss    

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Improvement of aerodynamic stability of suspension bridges with H-shaped simplified stiffening girder

Hiroshi KATSUCHI,Hitoshi YAMADA,Mayuko NISHIO,Yoko OKAZAKI

《结构与土木工程前沿（英文）》 2016年 第10卷 第1期   页码 93-102 doi: 10.1007/s11709-015-0311-0

摘要： Wind-tunnel study on the improvement of aerodynamic stability of simplified suspension-bridge girder structures was conducted with using a 1/40-scaled section model. Objective of the study is the development of an economically superior suspension bridge with 500–1,000 m center span length. The wind-tunnel test showed that an edge-girder type cross section exhibited large amplitude torsional vortex-induced vibration as well as torsional flutter at a low wind speed. Accordingly, aerodynamic countermeasures of open grating deck and triangular faring, and structural countermeasures of center stay, diagonal bracing and mass increase were tried to improve the aerodynamic stability. Finally, feasibility of the best combination to a full-scale bridge was examined by structural analysis.

关键词： suspension bridge     aerodynamics     simplified girder     wind-tunnel test    

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Water-dispersible nano-pollutions reshape microbial metabolism in type-specific manners: A metabolic

《环境科学与工程前沿（英文）》 2022年 第16卷 第9期 doi: 10.1007/s11783-022-1548-1

摘要：

• Water-dispersible nano-pollutions exhibit type-specific toxic effects on E. coli.

关键词： Nano-toxicity     Nano-plastics     Quantum dots     Microbial metabolite     Metabolic dysregulation    

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Laboratory investigation of emulsified asphalt binder modified with wood-derived nano-cellulose and nano

Yunge WEI; Jiayu WANG; Ruoyu LI; Ling XU; Feipeng XIAO

《结构与土木工程前沿（英文）》 2022年 第16卷 第11期   页码 1474-1485 doi: 10.1007/s11709-022-0869-2

摘要： Emulsified asphalt is the primary material for preventive maintenance and cold-mix paving, but its low cohesive strength and poor mechanical properties limit its wide application, even with polymer modification. In this study, Styrene-Butadiene Rubber (SBR) emulsified asphalt was modified with nano-cellulose materials, namely nano paper-cellulose (NPC) and wood-derived nano-cellulose (WDC), to improve its properties. A novel preparation method of nano-cellulose solution was developed, including blending, ultrasonic stirring, and centrifugal treatment. Four types of nano-cellulose solution (0.5% NPC, 0.5%, 1.0%, and 1.5% WDC by weight of water) were selected. The microscopy analysis indicated that 0.5% WDC emulsion had a smaller particle size than 1.5% WDC emulsion. The rheology test indicated that WDC modified residue improved rutting resistance with the increased solution dosage due to the cross-linking effect, but its creep-and-recovery performance was worse than that of SBR emulsion residue. The NPC modified binder had a higher rutting factor than WDC modified binder at the same dosage after short-term aging. In addition, 1.0% WDC could be regarded as the optimal dosage in terms of fatigue and low-temperature performance. Furthermore, Fourier Transform Infrared Spectroscopy (FTIR) results showed that 0.5% NPC modified residue performed better in long-term aging resistance compared with 0.5%WDC modified asphalt.

关键词： nano-cellulose     emulsified asphalt binder     dispersion     rheological properties     Fourier transform infrared spectroscopy    

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Limit span of self-anchored cable-stayed suspension cooperation system bridge based on strength

Zhe ZHANG , Huili WANG , Xiaomeng GE , Sifeng QIN ,

《结构与土木工程前沿（英文）》 2009年 第3卷 第3期   页码 286-291 doi: 10.1007/s11709-009-0045-y

摘要： The limit span of self-anchored cable-stayed suspension bridge is deduced. The relations among the geometrical parameters, loads and material characteristics are also analyzed. Based on the material strength and commonly used materials, the limit spans of self-anchored cable-stayed suspension bridges with concrete girder or steel girder under vertical static load are discussed in detail. The corresponding upper limit spans and the effect of the factors on the span are given. The results indicate that increasing rise-span ratio, height-span ratio and cable-stayed segment length or reducing the second dead load could increase the cooperation system span.

关键词： cable-stayed suspension     self-anchored     limit span    

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标题 作者 时间 类型 操作

β-Nickel hydroxide cathode material for nano-suspension redox flow batteries

Yue LI, Cheng HE, Elena V. TIMOFEEVA, Yujia DING, Javier PARRONDO, Carlo SEGRE, Vijay RAMANI

期刊论文

Optimal design and development of PV-wind-battery based nano-grid system: A field-on-laboratory demonstration

B. TUDU, K. K. MANDAL, N. CHAKRABORTY

期刊论文

Characterization and comparison of organic functional groups effects on electrolyte performance for vanadium redox flowbattery

期刊论文

Pressure drop analysis on the positive half-cell of a cerium redox flow battery using computational fluid

Fernando F. Rivera, Berenice Miranda-Alcántara, Germán Orozco, Carlos Ponce de León, Luis F. Arenas

期刊论文

Redox flow batteries—Concepts and chemistries for cost-effective energy storage

Matthäa Verena HOLLAND-CUNZ, Faye CORDING, Jochen FRIEDL, Ulrich STIMMING

期刊论文

End-of-life batteries management and material flow analysis in South Korea

Hyunhee Kim, Yong-Chul Jang, Yeonjung Hwang, Youngjae Ko, Hyunmyeong Yun

期刊论文

用于固定式大规模储能的液流电池

尹彦斌, 李先锋

期刊论文

Cumulant-based correlated probabilistic load flow considering photovoltaic generation and electric vehicle

Nitesh Ganesh BHAT, B. Rajanarayan PRUSTY, Debashisha JENA

期刊论文

A brief review on key technologies in the battery management system of electric vehicles

Kailong LIU, Kang LI, Qiao PENG, Cheng ZHANG

期刊论文

Investigations concerning seismic response control of self-anchored suspension bridge with MR dampers

YANG Menggang, HU Jianhua

期刊论文

Mechanical performance analysis and stiffness test of a new type of suspension bridge

期刊论文

Improvement of aerodynamic stability of suspension bridges with H-shaped simplified stiffening girder

Hiroshi KATSUCHI,Hitoshi YAMADA,Mayuko NISHIO,Yoko OKAZAKI

期刊论文

Water-dispersible nano-pollutions reshape microbial metabolism in type-specific manners: A metabolic

期刊论文

Laboratory investigation of emulsified asphalt binder modified with wood-derived nano-cellulose and nano

Yunge WEI; Jiayu WANG; Ruoyu LI; Ling XU; Feipeng XIAO

期刊论文

Limit span of self-anchored cable-stayed suspension cooperation system bridge based on strength

Zhe ZHANG , Huili WANG , Xiaomeng GE , Sifeng QIN ,

期刊论文